Finding Molarity of an Unknown Solution

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Molarity describes the relationship between moles of a solute and the volume of a solution.^[1] To calculate molarity, you can start with moles and volume, mass and volume, or moles and milliliters. Plugging these variables into the basic formula for calculating molarity will give you the correct answer.

1. 1

   Know the basic formula for calculating molarity. Molarity is equal to the number of moles of a solute divided by the volume of the solution in liters. As such, it is written as: molarity = moles of solute / liters of solution

   • Example problem: What is the molarity of a solution containing 0.75 mol NaCl in 4.2 liters?

2. 2

   Examine the problem. Finding molarity demands that you have the number of moles and the number of liters. If the problem provides each of these figures, no preliminary calculations are needed.

   • Example problem:
     • Moles = 0.75 mol NaCl
     • Volume = 4.2 L

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3. 3

   Divide the number of moles by the number of liters. The resulting quotient will give you the number of moles per liter of solution, otherwise known as molarity.

   • Example problem: molarity = moles of solute / liters of solution = 0.75 mol / 4.2 L = 0.17857142

4. 4

   Write your answer. Round off the number of digits after the decimal point to two or three, depending on your instructor's preference. When you write out the answer, abbreviate "molarity" with "M" and state the chemical abbreviation of the solute involved.

   • Example problem: 0.179 M NaCl

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1. 1

   Know the basic formula for calculating molarity. Molarity expresses the relationship between the number of moles of a solute per liters of solution, or the volume of that solution. In formula form, molarity is expressed as: molarity = moles of solute / liters of solution ^[2]

   • Example problem: What is the molarity of a solution made by dissolving 3.4 g of KMnO₄ in 5.2 liters of water?

2. 2

   Examine the problem. Finding molarity demands that you have the number of moles and the number of liters. If you are not provided with the number of moles but you do have the volume and mass of the solution, you will need to use these two figures to calculate the number of moles before continuing on.

   • Example problem:
     • Mass = 3.4 g KMnO₄
     • Volume = 5.2 L

3. 3

   Find the molar mass of the solute. To calculate the number of moles from the mass or grams of solute used, you must first determine the molar mass of the solute.^[3] This can be done by adding together the separate molar masses of each element found in the solution. Find the molar mass of each element using the periodic table of elements. Make sure that you count the atoms for each element and calculate the molar mass of each of the atoms.

   • Example problem:
     • Molar mass of K = 39.1 g
     • Molar mass of Mn = 54.9 g
     • Molar mass of O = 16.0 g (The solute contains 4 O atoms, so count the 16g 4 times.)
     • Total molar mass = K + Mn + O + O + O + O = 39.1 + 54.9 + 16 + 16 + 16 + 16 = 158.0 g

4. 4

   Convert the grams into moles. Now that you have the molar mass of the solute, you need to multiply the number of grams of solute in the solution by a conversion factor of 1 mole over the formula weight (molar mass) of the solute. This will give you the number of moles of the solute for this equation.^[4]

   • Example problem: grams of solute * (1/molar mass of solute) = 3.4 g * (1 mol / 158 g) = 0.0215 mol
   • The grams units of the solute and solute mass cancel each other out so you are left with mol units.

5. 5

   Divide the number of moles by the number of liters. Now that you have the number of moles, you can divide this value by the number of liters of solution in order to find the molarity.

   • Example problem: molarity = moles of solute / liters of solution = 0.0215 mol / 5.2 L = 0.004134615

6. 6

   Write your answer. You should round off the number of digits after the decimal point to the place requested by your instructor. Usually, this will be two or three places after the decimal point. Additionally, when you write out the answer, abbreviate "molarity" with "M" and state the solute involved.

   • Example problem: 0.004 M KMnO₄

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1. 1

   Know the basic formula for calculating molarity. In order to find molarity, you need to calculate the number of moles of solute for a solution per liter of solution. Milliliters cannot be used. The general formula used to express molarity is written as: molarity = moles of solute / liters of solution ^[5]

   • Example problem: What is the molarity of a solution containing 1.2 moles CaCl₂ in 2905 milliliters?

2. 2

   Examine the problem. Calculating molarity requires you to have the number of moles and the number of liters. If you are provided with the volume in milliliters instead of liters, you will need to convert the volume into liters before continuing your calculations.

   • Example problem:
     • Moles = 1.2 mol CaCl₂
     • Volume = 2905 ml

3. 3

   Convert the milliliters into liters. ^[6] Find the number of liters by dividing the number of milliliters by 1000, since there are 1000 milliliters per 1 liter. Note that you could also simply move the decimal point to the left three places.

   • Example problem: 2905 ml * (1 L / 1000 ml) = 2.905 L

4. 4

   Divide the number of moles by the number of liters. Now that you have the number of liters, you can divide the number of moles of solute by this value in order to find the molarity of the solution.

   • Example problem: molarity = moles of solute / liters of solution = 1.2 mol CaCl₂ / 2.905 L = 0.413080895

5. 5

   Write your answer. Round off the number of digits after the decimal point to the amount requested by your instructor (usually two or three places). When you write out the answer, you should also abbreviate "molarity" with "M," and state the solute.

   • Example problem: 0.413 M CaCl₂

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1. 1

   Find the molarity of a solution made by dissolving 5.2 g of NaCl in 800 ml of water. Identify the values provided to you in the problem: mass in grams and volume in milliliters.

   • Mass = 5.2 g NaCl
   • Volume = 800 ml water

2. 2

   Find the molar mass of NaCl. Do this by adding together the molar mass of sodium, Na, and the molar mass of chlorine, Cl.

   • The molar mass of Na = 22.99 g
   • The molar mass of Cl = 35.45 g
   • The molar mass of NaCl = 22.99 + 35.45 = 58.44 g

3. 3

   Multiply the mass of the solute by its molar mass conversion factor. In this instance, the molar mass of NaCl is 58.44 g, so the conversion factor is 1 mol / 58.44 g.

   • Moles NaCl = 5.2 g NaCl * (1 mol / 58.44 g) = 0.08898 mol = 0.09 mol

4. 4

   Divide 800 ml of water by 1000. Since there are 1000 milliliters per liter, you will need to divide the number of milliliters in this problem by 1000 in order to find the number of liters.

   • You could also look at it as multiplying 800 ml by a conversion factor of 1 L / 1000 ml.
   • To hasten the process, you could simply move the decimal point three places to the left instead of multiplying or dividing anything.
   • Volume = 800 ml * (1 L / 1000 ml) = 800 ml / 1000 ml = 0.8 L

5. 5

   Divide the number of moles of solute by the number of liters of solution. In order to find the molarity, you need to divide 0.09 mol, the number of moles of the solute NaCl, by 0.8 L, the volume of the solution in liters.

   • molarity = moles of solute / liters of solution = 0.09 mol / 0.8 L = 0.1125 mol/L

6. 6

   Tidy up your answer. Round your answer off to two or three decimal places and abbreviate molarity with "M."

   • Answer: 0.11 M NaCl

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Add New Question

• Question

  What is the formula for a mole?

  

  No. of moles = (Given mass of compound in the question)/Molecular mass of the given compound

• Question

  What is the difference between molarity and molar mass?

  

  Molarity is a measure and unit of concentration. It is used to express concentration of a particular solution. On the other hand, molar mass is a unit of mass. It is the mass of 1 mole of a substance.

• Question

  How can I calculate molarity if concentration is given as percentage?

  

  Convert the percentage to a decimal by moving the decimal point left two places. For example; 98% would become 0.98, and 6% would become 0.06.

• Question

  What is the symbol of molarity?

  

  Molarity is denoted by M.

• Question

  How do I calculate molarity without the moles?

  

  You can get your moles by taking the molar mass of each of the elements in the solute and adding them together. (You can get the molar mass of each element off the periodic chart. It's usually the number underneath the symbol.) Don't forget to multiply that number if there is more than one of the element, like H2 or 3NO4. Once you have that total molecular mass for the solute, the molecular mass is always equal to one mole of the solute, so you multiply your grams of mass by 1 mole divided by the molecular mass, which is grams. This will leave you with a division problem. Do it; the answer is in moles because the grams cancelled out.Then, go ahead and do your formula.

• Question

  What is the molarity of 5%(m/v) potassium carbonate (mw=138.21 g/mol)?

  

  Better if you solve it yourself, but here is a shortcut. Molarity=10a/molar mass. Here a= number of percent given in the question.

• Question

  How can I calculate molarity when I am given mass in milliliters?

  

  Divide the mass by molar mass (mass/molar mass) and convert the milliliters into liters (ml/1000). Now you have moles of solute and liters of solution. Molarity=moles of solute/liters of solution.

• Question

  How do I calculate the volume needed to have a specific molarity?

  

  By giving the values of molarity and number of moles in the formula of molarity.

• Question

  Can I find the molarity if the liters (or ml) are not given?

  

  Qwertywater

  Community Answer

  There are different methods for finding molarity. If you don't have volume you can use another formula, like mass divided by relative molecular mass.

• Question

  How can I calculate volume in molarity?

  

  Molarity = no of moles of solute/volume of solvent.

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Article SummaryX

To calculate molarity, divide the number of moles of solute by the volume of the solution in liters. If you don't know the number of moles of solute but you know the mass, start by finding the molar mass of the solute, which is equal to all of the molar masses of each element in the solution added together. Once you have the molar mass, multiply the number of grams of solute by 1 over the molar mass to convert the grams into moles. Finally, divide the number of moles by the volume of the solution to get the molarity. To learn how to calculate molarity using moles and milliliters, scroll down!

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Finding Molarity of an Unknown Solution

Source: https://www.wikihow.com/Calculate-Molarity

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